原创力文档- 1、本文档共120页，可阅读全部内容。
- 2、原创力文档（book118）网站文档一经付费（服务费），不意味着购买了该文档的版权，仅供个人/单位学习、研究之用，不得用于商业用途，未经授权，严禁复制、发行、汇编、翻译或者网络传播等，侵权必究。
- 3、本站所有内容均由合作方或网友上传，本站不对文档的完整性、权威性及其观点立场正确性做任何保证或承诺！文档内容仅供研究参考，付费前请自行鉴别。如您付费，意味着您自己接受本站规则且自行承担风险，本站不退款、不进行额外附加服务；查看《如何避免下载的几个坑》。如果您已付费下载过本站文档，您可以点击 这里二次下载。
- 4、如文档侵犯商业秘密、侵犯著作权、侵犯人身权等，请点击“版权申诉”（推荐），也可以打举报电话：400-050-0827(电话支持时间：9:00-18:30)。
Class-1:1.IntroductionPolymerPolymerhistoryPolymerscience
AsEarlyasLifeBegan:naturalpolymers–BIOMACROMOLECULESPolysaccharides,DNA,RNA,starch,cellulose,chitin,etc.WhatarePolymers?DNARNA
CelluloseChitinWhatarePolymers?
AsBroadasinDailyLife:syntheticpolymerspolystyrenecis-polyisoprenepoly(vinylpyrrolidone)WhatarePolymers?
Polymerpolymerisasubstancecomposedofmoleculeswhichhavelongsequenceofoneormorespeciesofatomsorgroupsofatomslinkedtoeachotherbyprimary,usuallycovalentbonds.SyntheticPolymers---DefinitionMacromoleculemacromoleculesareformedbylinkingtogethermonomermoleculesthroughchemicalreaction(polymerization).PolymerandMacromoleculeusedinterchangeably.
FocusofThisCourse–SYNTHETICPOLYMER!!!NaturalPolymersSyntheticPolymersRepeatingunitsmanykindsoneorafewkindsStructurewell-definedpoorlydefinedMWdistribution1.0forproteinsfrom1.0to~30DifferencesbetweenNaturalPolymersandSyntheticPolymersSyntheticPolymers---Definition
PolymerderivedfromclassicalGreekAutumn2013SyntheticPolymers---Definition—M—M—M—M—M—M—Or—(M)n—Poly.....mersmanyunitsLong-chain-likemoleculesormacromoleculesconsistingofmanyrepeatingunits(monomers)thatarecovalentlylinked,insteadofphysically-associatedaggregates.Molecularweighthigherthan~10,000g/mol(differentfromoligomers,whichiscomposedofafewrepeatingunits)
Rg=N0.5a=13.0nmrandomcoilRgextendedchainLex=Na=1100.0nm=1.1mmMW=105g/molN=7143CH2polyethylene(PE)CH2=CH2ethyleneAnExample---Polyethylene
SomeBasicDefinitionsPOLYMERAlargemoleculemadeupofsmallbuildingblocksMONOMERSThebuildingblocksHOMOPOLYMERWhatyougetifthebuildingblocksareallthesameCOPOLYMERAp
文档评论（0）