Firmenich talk Knochel格式反应.ppt

Functionalized Mg-Organometallics in Organic SynthesisFirmenich, March, 31. 2006  LiCl- Accelerated Organometallic Reactions General Preparation of Functionalized Organozinc Reagents General Preparation of Functionalized Organozinc Reagents (1) General Preparation of Functionalized Organozinc Reagents (2) General Preparation of Functionalized Organozinc Reagents (3) General Preparation of Functionalized Organozinc Reagents (4) General Preparation of Functionalized Organozinc Reagents (5) General Preparation of Functionalized Organomagnesium Reagents Functionalized Magnesium Organometallics Ester Functionalized Arylmagnesium Reagents Synthesis of Functionalized magnesiated Heterocycles Substituted Nitro-Arylmagnesium Reagents Chemoselective Br/Mg-Exchange Br-Mg Exchange with bromobenzonitriles The Halogen-Metal Exchange for the Preparation of Functionalized Organometallics Br-Mg Exchange with Polybromobenzenes(3) Br-Mg Exchange with Polybromobenzenes (2) Synthesis of Keto-Substituted Magnesium Compounds Synthesis of Keto-Substituted Magnesium Compounds Synthesis of Magnesiated Heterocycles via Selective Deprotonations (1) Synthesis of Magnesiated Heterocycles via Selective Deprotonations (2) Synthesis of Magnesiated Heterocycles via Selective Deprotonations (3) Synthesis of Magnesiated Heterocycles via Selective Deprotonations (4) Synthesis of Magnesiated Heterocycles via Selective Deprotonations (5) Synthesis of Magnesiated Heterocycles via Selective Deprotonations (6) Synthesis of Magnesiated Heterocycles via Selective Deprotonations (7) Double Functionalization of Pyrimidines (8) Functionalization of Pyrimidines in position 5 (9) Synthesis of Magnesiated Heterocycles via Selective Deprotonations (8) Synthesis of Magnesiated Heterocycles via Selective Deprotonations (9) Couplings in the Absence of Transition Metals (1) Couplings in the Absence of Transition Metals (2) Couplings in the Absence of Transition Metals (3) Couplings in the Absence of Transit