同位素文献翻译.docx

同位素地球化学文献翻译磷酸盐中的微沉积以及δ18O关于古气候和生物地球化学的研究姓名：王夕瑞学号：20141003008班级：015142指导老师：吴元保日期：2017.7.2AbstractPhosphate oxygen isotope ratios provide a powerful tool for paleoclimate reconstructi14on and the study of phosphorus biogeochemistry in aquatic systems. The temperature dependent offset between the oxygen isotope composition of phosphate and water in biogenic minerals and in solutions has been used extensively in paleoclimate research and the study of phosphorus cycling in aquatic and soil environments. Sample sizes are small in many applications, e.g., serial sampling of mammalian tooth enamel for paleoseasonality studies, the use of conodont elements for climate and ocean δ18O reconstruction, or the isolation and analysis of dissolved phosphate from marine and freshwater environments in biogeochemistry studies. This has pushed the development of techniques that allow for processing and analysis of a few micromoles of phosphate.Current approaches to phosphate oxygen isotopic composition (δ18Op) determination require purification of phosphate as silver phosphate (Ag3PO4). The techniques for the final precipitation of Ag3PO4 fall into two categories: slow vs. rapid microprecipitations. We have tested both and identify artifacts that impact measured δ18Op values resulting from commonly used methods for rapid Ag3PO4 precipitation. In particular, commonly used methods are prone to (a) incomplete precipitation of phosphate, with associated isotopic fractionation, and (b) the production of silver oxide contaminants whose oxygen isotope composition is sensitive to the δ18O of water used to prepare the precipitation reagent solution. These artifacts are commonly on the order of 0.5 to 2‰, which is subtle enough to go undetected in many studies, but large enough to cause errors in temperature estimates on the order of 2–8 °C.Slow microprecipitations lead to complete precipitation of phosphate without contaminating O-bearing phases. We develop a rapid precipitation technique that