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CO2+DME混合体系跨临界吸收式动力循环热转换机理
摘要关键词 ;;Heat Conversion Mechanism for CO2+Dimethyl Ether Absorption Power Trans-critical Cycle
FENG Le-jun, ZHENG Dan-xing, SHI Lin(
(Tsinghua University, Haidian District Beijing 100084, China)
(Tel: 010 Email: rnxsl@mail.tsinghua.edu.cn)
Abstract CO2+DME binary system was considered to be the working fluid of absorption power cycle in this work. The “Chemical heat engine” concept was introduced, and divided the cycle into two sub-cycles: Chemical heat engine sub-cycle and Heat engine sub-cycle. Then comparatively analyzed the essential reason of trans-critical operation condition was better than sub-critical and supercritical based on the operation pressure and the degree of match the heat source. An absorption power cycle simulation program was established, and the PR equation was selected as the calculation model. Then the composition, flow rate, enthalpy value and entropy value of the cycle streams were calculated respectively. According to the T-s and lg p-h diagrams of the cycle, the coupling relationship and heat conversion mechanism of the two sub-cycles were analyzed. As the result shows, due to the coupling of Chemical heat engine sub-cycle, the heat achieved gradient utilization and the turbine outlet pressure has reduced, and the heat conversion work efficiency of Heat engine was improved from 14.06% to 15.79%. Finally, according to the parameter analysis method, the influence of the pressure to the heat conversion work efficiency for Chemical heat engine sub-cycle was explored at different absorption temperature (25, 30, 35 and 40) °C. The results show that reduces the operation pressure of Chemical heat engine sub-cycle can increase the heat conversion work efficiency and improve energy utilization.
Key words Absorption power cycle; Chemical heat engine; Energy utilization; Heat conversion work efficiency; CO2+DME
0.前言CO2+DME,并基于文献报道的气液相平衡数据,建立了CO2+DME跨临界吸收式动力循环模拟模型并获得了循环的物流参数。基于子循环划分的方法,将循环划分为热机子循环和化学热机子循,分别分析了两
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